Stabilized zirconia-based sensors using WO3 electrode for detection of NO or NO2

被引:93
作者
Lu, G [1 ]
Miura, N [1 ]
Yamazoe, N [1 ]
机构
[1] Kyushu Univ, Grad Sch Engn Sci, Dept Mol & Mat Sci, Kasuga, Fukuoka 8168580, Japan
关键词
stabilized zirconia; oxide electrode; mixed potential; nitrogen oxides; gas sensor;
D O I
10.1016/S0925-4005(99)00398-6
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A stabilized zirconia-based electrochemical device, the sensing electrode of which was provided with a single-metal oxide, was tested for detection of NO and NO2 at high temperature, Among the many single-metal oxides examined, WO3 was found to give the best sensing properties to NO and NO2 at 500-700 degrees C. The EMF response of the WO3-attached device was almost linear to the logarithm of NO or NO2 concentration. It also gave speedy response and recovery kinetics to NO or NO2. The device gave very small cross-sensitivities to H-2, CO, CH4, CO2 and water vapor. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:125 / 127
页数:3
相关论文
共 4 条
[1]   TUNGSTEN OXIDE-BASED SEMICONDUCTOR SENSOR HIGHLY SENSITIVE TO NO AND NO2 [J].
AKIYAMA, M ;
TAMAKI, J ;
MIURA, N ;
YAMAZOE, N .
CHEMISTRY LETTERS, 1991, (09) :1611-1614
[2]   High-temperature sensors for NO and NO2 based on stabilized zirconia and spinel-type oxide electrodes [J].
Lu, G ;
Miura, N ;
Yamazoe, N .
JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (08) :1445-1449
[3]   Mixed potential type NOx sensor based on stabilized zirconia and oxide electrode [J].
Miura, N ;
Lu, GY ;
Yamazoe, N ;
Kurosawa, H ;
Hasei, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (02) :L33-L35
[4]   Solid-state amperometric NO2 sensor using a sodium ion conductor [J].
Miura, N ;
Iio, M ;
Lu, GY ;
Yamazoe, N .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 35 (1-3) :124-129