Chiral catalysis on solids

被引：105

作者：

Baiker, A ^{[1
]}

机构：

[1] ETH Zentrum, Swiss Fed Inst Technol, Tech Chem Lab, CH-8092 Zurich, Switzerland

来源：

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE | 1998年 / 3卷 / 01期

关键词：

D O I：

10.1016/S1359-0286(98)80070-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Significant progress in the development of catalysts based on chirally modified metals, chiral polymers and heterogenized chiral metal complexes has been driven by experimental work to unravel the crucial properties of these complex catalytic systems. Experimental and theoretical studies aiming at rationalizing the structure of enantiodifferentiating transition states are indispensable to move from empirical to rational design. A few recent examples indicate the potential of such design strategy.

引用

页码：86 / 93

页数：8

共 57 条

[1] CHIRAL POLYMER CATALYSTS IN PREPARATIVE ORGANIC-CHEMISTRY - A CRITICAL OVERVIEW [J].

AGLIETTO, M ;

CHIELLINI, E ;

DANTONE, S ;

RUGGERI, G ;

SOLARO, R .

PURE AND APPLIED CHEMISTRY, 1988, 60 (03) :415-430

[2] Progress in asymmetric heterogeneous catalysis: Design of novel chirally modified platinum metal catalysts [J].

Baiker, A .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 115 (03) :473-493

[3]

BAIKER A, 1997, HDB HETEROGENEOUS CA, V5, P2422

[4]

BENTLEY PA, 1997, J CHEM SOC CHEM COMM, P739

[5] Enantioselective hydrogenation of alpha-ketoesters using cinchona modified platinum catalysts and related systems: A review [J].

Blaser, HU ;

Jalett, HP ;

Muller, M ;

Studer, M .

CATALYSIS TODAY, 1997, 37 (04) :441-463

[6]

BLASER HU, 1995, CHIRAL REACTIONS IN HETEROGENEOUS CATALYSIS, P33

[7]

BODMER M, 1998, IN PRESS CATALYSIS O

[8] Enantioselective hydrogenation of pyruvic acid oxime to alanine on Pd/alumina [J].

Borszeky, K ;

Mallat, T ;

Aeschiman, R ;

Schweizer, WB ;

Baiker, A .

JOURNAL OF CATALYSIS, 1996, 161 (01) :451-458

[9] Enantioselective hydrogenation of 2-methyl-2-pentenoic acid over cinchonidine-modified Pd/alumina [J].

Borszeky, K ;

Mallat, T ;

Baiker, A .

CATALYSIS LETTERS, 1996, 41 (3-4) :199-202

[10]

CANALI L, 1997, J CHEM SOC CHEM COMM, P123

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