An artificial antenna complex containing four Ru(bpy)32+-type chromophores as light-harvesting components and a Ru(bpy)(CN)42- subunit as the energy trap.: A structural motif which resembles the natural photosynthetic systems

被引：36

作者：

Loiseau, F ^{[1
]}

Marzanni, G

Quici, S

Indelli, MT

Campagna, S

机构：

[1] Univ Messina, Dept Chem, I-98166 Messina, Italy

[2] Univ Milan, CNR, ISTM, I-20133 Milan, Italy

[3] Univ Milan, Dipartimento Chim Organ & Ind, I-20133 Milan, Italy

[4] Univ Ferrara, Dipartmento Chim, I-44100 Ferrara, Italy

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 02期

关键词：

D O I：

10.1039/b211122e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A cyclam subunit bearing four light-harvesting Ru(bpy)(3)(2+) type species is connected to a Ru(II) compound having low-lying excited states (energy trap) by hydrogen bonding: the light absorbed by the light-harvesting elements is funnelled to the energy trap with high efficiency.

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页码：286 / 287

页数：2

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