Incorporation and manipulation of coronene in an organic template structure

被引:217
作者
Griessl, SJH
Lackinger, M
Jamitzky, F
Markert, T
Hietschold, M
Heckl, WA [1 ]
机构
[1] Univ Munich, Dept Geo & Umweltwissensch, Munich, Germany
[2] Tech Univ Chemnitz, Inst Phys, Chemnitz, Germany
关键词
D O I
10.1021/la049441c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A two-dimensional molecular template structure of 1,3,5-benzenetricarboxylic acid (trimesic acid, TMA) was formed on a highly oriented pyrolytic graphite surface (HOPG) by self-assembly at the liquid-solid interface. Scanning tunneling microscopy (STM) investigations show high-resolution images of the porous structure on the surface. After the host structure was created, coronene molecules were inserted as guest molecules into the pores. STM results indicate that some of the guest molecules rotate inside their molecular bearing. Further investigations show that single coronene molecules can be directly kicked out of their pores by means of STM.
引用
收藏
页码:9403 / 9407
页数:5
相关论文
共 32 条
[1]  
Barth JV, 2000, ANGEW CHEM INT EDIT, V39, P1230, DOI 10.1002/(SICI)1521-3773(20000403)39:7<1230::AID-ANIE1230>3.0.CO
[2]  
2-I
[3]   Influence of confinement on the solvation and rotational dynamics of coumarin 153 in ethanol [J].
Baumann, R ;
Ferrante, C ;
Kneuper, E ;
Deeg, FW ;
Bräuchle, C .
JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (14) :2422-2430
[4]   Self-organized growth of semiconductor nanostructures for novel light emitters [J].
Bimberg, D ;
Heinrichsdorff, F ;
Ledentsov, NN ;
Shchukin, VA .
APPLIED SURFACE SCIENCE, 2000, 159 :1-7
[5]   Self-assembly of 1-nitronaphthalene on Au(111) [J].
Böhringer, M ;
Morgenstern, K ;
Schneider, WD ;
Wühn, M ;
Wöll, C ;
Berndt, R .
SURFACE SCIENCE, 2000, 444 (1-3) :199-210
[6]   Self-organized growth of cluster arrays [J].
Bromann, K ;
Giovannini, M ;
Brune, H ;
Kern, K .
EUROPEAN PHYSICAL JOURNAL D, 1999, 9 (1-4) :25-28
[7]   Supramolecular assemblies of trimesic acid on a Cu(100) surface [J].
Dmitriev, A ;
Lin, N ;
Weckesser, J ;
Barth, JV ;
Kern, K .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (27) :6907-6912
[8]   2175 Å and 3.4 micron absorption bands and carbon depletion in the diffuse interstellar medium [J].
Duley, WW ;
Seahra, SS .
ASTROPHYSICAL JOURNAL, 1999, 522 (02) :L129-L132
[9]  
Ermer O, 2001, HELV CHIM ACTA, V84, P1268, DOI 10.1002/1522-2675(20010613)84:6<1268::AID-HLCA1268>3.0.CO
[10]  
2-Z