Ion exchange behavior of the NH4TiOPO4 based exchanger

被引:9
作者
Bortun, AI [1 ]
Bortun, LN [1 ]
Clearfield, A [1 ]
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
关键词
D O I
10.1080/07366299808934546
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Several compounds of the general formula (NH4)((1-x))HxTiOPO4 . nH(2)O (x=0.45-0.75) were prepared by acid treatment of ammonium titanyl phosphate (NTP) at elevated temperature (80-90 degrees C). The protonic phases of the NTP were characterized by elemental analysis, TGA, FT-IR, MAS P-31 NMR and X-ray diffraction. Their ion exchange behavior towards alkali, alkaline earth and some transition metal ions in pure single ion solutions and mixtures was studied. A high capacity and selectivity for potassium and lead makes it promising for certain types of waste treatment and selected analytical separations.
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页码:669 / 681
页数:13
相关论文
共 24 条
[1]  
ABE M, 1995, ION EXCHANGE SOLVENT, V12
[2]  
Alberti G, 1987, RECENT DEV ION EXCHA
[3]  
Amphlett C.B., 1964, INORGANIC ION EXCHAN
[4]  
Anthony R. G., 1993, Waste Management, V13, P503, DOI 10.1016/0956-053X(93)90080-G
[5]  
ASHIROV A, 1983, ION EXCHANGE TREATME
[6]   Hydrolytic stability of amorphous titanium and zirconium phosphates [J].
Bortun, AI ;
Garcia, JR ;
Budovitskaya, TA ;
Strelko, VV ;
Rodriguez, J .
MATERIALS RESEARCH BULLETIN, 1996, 31 (05) :487-496
[7]   Synthesis and characterization of ion exchange properties of spherically granulated titanium phosphate [J].
Bortun, AI ;
Bortun, LN ;
Clearfield, A ;
Khainakov, SA ;
Strelko, VV ;
Khryashevskii, VN ;
Kvashenko, AP ;
Voitko, II .
SOLVENT EXTRACTION AND ION EXCHANGE, 1997, 15 (03) :515-532
[8]  
Bortun L. N., 1996, ION EXCHANGE DEV APP, P313
[9]  
CHERNORUKOV NG, 1982, RUSS J INORG CHEM, V27, P1728
[10]   PREPARATION, STRUCTURE, AND ION-EXCHANGE PROPERTIES OF NA4TI9O20.XH2O [J].
CLEARFIELD, A ;
LEHTO, J .
JOURNAL OF SOLID STATE CHEMISTRY, 1988, 73 (01) :98-106