The characterisation of supported platinum nanoparticles on carbon used for enantioselective hydrogenation: A combined electrochemical - STM approach

被引：29

作者：

Attard, GA

Ahmadi, A

Jenkins, DJ

Hazzazi, OA

Wells, PB

Griffin, KG

Johnston, P

Gillies, JE

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

[2] Johnson Matthey, Royston SG8 5HE, England

来源：

CHEMPHYSCHEM | 2003年 / 4卷 / 02期

关键词：

catalysis; cyclic voltammetry; electrochemistry; enantioselectivity; nanoparticles; scanning probe microscopy; surface chirality;

D O I：

10.1002/cphc.200390021

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The action of chiral modifiers like cinchonine and cinchonidine in facilitating enationselectivity in heterogeneous catalysis is investigated using a combination of electrochemical and scanning probe methods. The surface chirality of corner kink sites is suggested as being crucial for chirality recognition at supported catalyst nanoparticles. Other aspects of chirality in relation to one, two, three and four dimensions are also discussed.

引用

页码：123 / 130

页数：8

共 31 条

[21] Adsorption of chiral alcohols on ''chiral'' metal surfaces [J].