Enhanced enantioselectivity and remarkable acceleration on the lipase-catalyzed transesterification using novel ionic liquids

被引：117

作者：

Itoh, T ^{[1
]}

Han, SH ^{[1
]}

Matsushita, Y ^{[1
]}

Hayase, S ^{[1
]}

机构：

[1] Tottori Univ, Fac Engn, Dept Mat Sci, Tottori 6808552, Japan

来源：

GREEN CHEMISTRY | 2004年 / 6卷 / 09期

关键词：

D O I：

10.1039/b405396f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel imidazolium salt ionic liquids were prepared derived from polyoxyethylene( 10) cetyl sulfate and used as an additive for lipase-catalyzed transesterification in organic solvent; a remarkable enhanced enantioselectivity was obtained when the salt was added in 3 to 10 mol% vs. substrate in the Pseudomonas cepacia lipase-catalyzed transesterification of 1-phenylethanol using vinyl acetate in a diisopropyl ether or hexane solvent system. There was a remarkable acceleration when the lipase was coated with this novel ionic liquid and used as catalyst for transesterification in i-Pr2O or in hexane.

引用

页码：437 / 439

页数：3

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