Preparation of tellurite thin films from tellurium isopropoxide precursor by sol-gel processing

被引:29
作者
Hodgson, SNB [1 ]
Weng, L [1 ]
机构
[1] Loughborough Univ Technol, Inst Polymer Technol & Mat Engn, Loughborough LE11 3TU, Leics, England
关键词
D O I
10.1016/S0022-3093(00)00254-4
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
An investigation into the use of sol-gel processing for the fabrication of tellurite (TeO2) thin films from tellurium isopropoxide (Te(OPri)(4)) is described. Commercial tellurium isopropoxide was characterised structurally and its hydrolysis was studied. The work also involved the identification of suitable strategies to control the hydrolysis reaction of tellurium isopropoxide to allow thin films to be successfully produced and characterised. The transmittance of thin films was investigated, together with their phase composition. The success in producing these thin films by sol-gel processing provides new opportunities for making tellurite thin film devices for practical applications, such as optical data storage and non-linear optical switching. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:195 / 200
页数:6
相关论文
共 16 条
[1]   INFRARED SPECTRAL INVESTIGATION OF TELLURITES [J].
ARNAUDOV, M ;
DIMITROV, V ;
DIMITRIEV, Y ;
MARKOVA, L .
MATERIALS RESEARCH BULLETIN, 1982, 17 (09) :1121-1129
[2]   ALUMINUM SEC-BUTOXIDE MODIFIED WITH ETHYLACETOACETATE - AN ATTRACTIVE PRECURSOR FOR THE SOL-GEL SYNTHESIS OF CERAMICS [J].
BABONNEAU, F ;
COURY, L ;
LIVAGE, J .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1990, 121 (1-3) :153-157
[3]   STRUCTURAL AND THERMAL-PROPERTIES OF SOME TELLURITE GLASSES [J].
BAHGAT, AA ;
SHALTOUT, II ;
ABUELAZM, AM .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1992, 150 (1-3) :179-184
[4]  
BRADLEY DC, 1978, METAL ALKOXIDE
[5]  
BRINKER CJ, 1990, SOL GEL SCI PHYSICS
[6]   THE OPTICAL-PROPERTIES OF TELLURITE GLASSES [J].
ELMALLAWANY, R .
JOURNAL OF APPLIED PHYSICS, 1992, 72 (05) :1774-1777
[7]   MEMORY SWITCHING OF V2O5-TEO2 GLASSES [J].
HIRASHIMA, H ;
IDE, M ;
YOSHIDA, T .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1986, 86 (03) :327-335
[8]  
HUBERTPFALZGRAF LG, 1987, NEW J CHEM, V11, P663
[9]   THE ELASTIC BEHAVIOR OF TEO2 GLASS UNDER UNIAXIAL AND HYDROSTATIC-PRESSURE [J].
LAMBSON, EF ;
SAUNDERS, GA ;
BRIDGE, B ;
ELMALLAWANY, RA .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1984, 69 (01) :117-133
[10]   CRYSTAL STRUCTURE OF TELLURIUM (4) CATECHOLATE TE(C6H4O2)2 [J].
LINDQVIST, O .
ACTA CHEMICA SCANDINAVICA, 1967, 21 (06) :1473-+