10a-Aza-10b-borapyrenes: Heterocyclic analogues of pyrene with internalized BN moieties

被引：224

作者：

Bosdet, Michael J. D. ^{[1
]}

Piers, Warren E. ^{[1
]}

Sorensen, Ted S. ^{[1
]}

Parvez, Masood ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 26期

关键词：

aromaticity; boron; cycloisomerization; fluorescence; heterocycles;

D O I：

10.1002/anie.200700591

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Très BN: The introduction of a B-N dipole into the internal positions of pyrene (see scheme) provides a novel platform for heterocyclic fluorescent species. Comparisons of the photophysical and redox properties between the CC and BN analogues reveal both similarities and differences. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4940 / 4943

页数：4

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