Recent developments in the chemistry of stable silylenes

被引：245

作者：

Hill, NJ ^{[1
]}

West, R ^{[1
]}

机构：

[1] Univ Wisconsin, Organosilicon Res Ctr, Dept Chem, Madison, WI 53706 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 24期

关键词：

D O I：

10.1016/j.jorganchem.2004.09.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This paper reviews progress in the field of thermally stable silylenes since 2000. Developments in the synthesis and characterization of new stable silylenes are discussed, followed by a summary of recent theoretical calculations upon model silylenes. The main part of the article concerns the reactivity patterns displayed by silylenes 1-4, which are discussed in terms of their behavior toward radical, organic, inorganic, and organometallic species. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：4165 / 4183

页数：19

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