Nonlinear chemical dynamics

被引:144
作者
Sagués, F
Epstein, IR
机构
[1] Univ Barcelona, Dept Quim Fis, E-08028 Barcelona, Spain
[2] Brandeis Univ, Dept Chem, Waltham, MA 02454 USA
[3] Brandeis Univ, Volen Ctr Complex Syst, Waltham, MA 02454 USA
关键词
D O I
10.1039/b210932h
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The interdisciplinary field of nonlinear chemical dynamics has grown significantly in breadth and depth over the past three decades. Its subject matter and applications encompass all branches of chemistry as well as areas of mathematics, physics, biology and engineering. In this Perspective, we present an overview of some of the key results of nonlinear chemical dynamics, with emphasis on those areas most likely to be of interest to inorganic chemists. We discuss the range of phenomenology from chemical oscillation to chaos to waves and pattern formation, as well as experimental methods, mechanistic considerations, theoretical techniques, and the results of coupling and external forcing.
引用
收藏
页码:1201 / 1217
页数:17
相关论文
共 195 条
[1]   The blue bottle experiment - Simple demonstration of self-organization [J].
Adamcikova, L ;
Sevcik, P .
JOURNAL OF CHEMICAL EDUCATION, 1998, 75 (12) :1580-1580
[2]   INFLUENCE OF ELECTRIC-FIELD ON ROTATING SPIRAL WAVES IN THE BELOUSOV-ZHABOTINSKY REACTION [J].
AGLADZE, KI ;
DEKEPPER, P .
JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (13) :5239-5242
[3]   SYSTEMATIC DESIGN OF CHEMICAL OSCILLATORS .16. BIRHYTHMICITY AND COMPOUND OSCILLATION IN COUPLED CHEMICAL OSCILLATORS - CHLORITE-BROMATE-IODIDE SYSTEM [J].
ALAMGIR, M ;
EPSTEIN, IR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (08) :2500-2502
[4]   SYSTEMATIC DESIGN OF CHEMICAL OSCILLATORS .15. A NEW TYPE OF BROMATE OSCILLATOR - THE BROMATE-IODIDE REACTION IN A STIRRED-FLOW REACTOR [J].
ALAMGIR, M ;
DEKEPPER, P ;
ORBAN, M ;
EPSTEIN, IR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (09) :2641-2643
[5]   EXPERIMENTAL-STUDY OF COMPLEX DYNAMICAL BEHAVIOR IN COUPLED CHEMICAL OSCILLATORS [J].
ALAMGIR, M ;
EPSTEIN, IR .
JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (13) :2848-2851
[6]   AN EXPERIMENTAL INVESTIGATION OF PERIODIC AND CHAOTIC ELECTROCHEMICAL OSCILLATIONS IN THE ANODIC-DISSOLUTION OF COPPER IN PHOSPHORIC-ACID [J].
ALBAHADILY, FN ;
SCHELL, M .
JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (07) :4312-4319
[7]   Excitability transitions and wave dynamics under spatiotemporal structured noise -: art. no. 066107 [J].
Alonso, S ;
Sagués, F ;
Sancho, JM .
PHYSICAL REVIEW E, 2002, 65 (06) :1-066107
[8]   Noise-induced Brownian motion of spiral waves -: art. no. 046205 [J].
Alonso, S ;
Sagués, F .
PHYSICAL REVIEW E, 2001, 63 (04)
[9]   Regular wave propagation out of noise in chemical active media -: art. no. 078302 [J].
Alonso, S ;
Sendiña-Nadal, I ;
Pérez-Muñuzuri, V ;
Sancho, JM ;
Sagués, F .
PHYSICAL REVIEW LETTERS, 2001, 87 (07) :78302-1
[10]  
ALONSO S, 2003, SCIENCE 0507