Na13K4Ga47.45:: a new sodium potassium gallide phase containing trimeric icosahedral gallium clusters

被引：11

作者：

Flot, D ^{[1
]}

Vincent, L ^{[1
]}

Tillard-Charbonnel, M ^{[1
]}

Belin, C ^{[1
]}

机构：

[1] Univ Montpellier 2, Lab Agregats Mol & Mat Inorgan, ESA 5072, F-34095 Montpellier 5, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270197015977

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Na13K4Ga47.45 was isolated from a melt prepared from the elements taken in the atomic proportion 3:1:12. It crystallizes in the trigonal R (3) over bar m space group [a = 16.325 (3), c = 35.135 (5) Angstrom]. The structure results from the packing of icosahedral Ga-12 units and trimeric Ga-28 units. The latter are formed by the condensation of three Gait units by triangular-face sharing. The interpolyhedral space is filled with K+ and Na+ cations.

引用

页码：174 / 175

页数：2

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