Subphthalocyanine enantiomers:: first resolution of a C3 aromatic compound by HPLC

被引:85
作者
Claessens, CG [1 ]
Torres, T [1 ]
机构
[1] Univ Autonoma Madrid, Fac Ciencias, Dept Quim Organ CI, E-28049 Madrid, Spain
关键词
boron heterocycles; chromatography; nitrogen heterocycles; resolution;
D O I
10.1016/S0040-4039(00)01056-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The constitutional isomers of chloro(2,9,16(17)triodosubphthalocianato)boron(III) have been separated by column chromatography on silica gel. Furthermore, the enantiomers of each of these C-1- and C-3-regioisomers have been resolved by HPLC on a chiral analytical column. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:6361 / 6365
页数:5
相关论文
共 25 条
  • [1] Claessens CG, 2000, EUR J ORG CHEM, V2000, P1603
  • [2] Claessens CG, 2000, CHEM-EUR J, V6, P2168, DOI 10.1002/1521-3765(20000616)6:12<2168::AID-CHEM2168>3.0.CO
  • [3] 2-N
  • [4] CIRCULAR-DICHROISM AND ABSOLUTE-CONFIGURATION OF C3-CHIRAL DERIVATIVES OF CYCLOTRIVERATRYLENE
    COLLET, A
    GOTTARELLI, G
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (01) : 204 - 205
  • [5] COLLET A, 1978, TETRAHEDRON LETT, V19, P1265
  • [6] Synthesis and nonlinear optical, photophysical, and electrochemical properties of subphthalocyanines
    del Rey, B
    Keller, U
    Torres, T
    Rojo, G
    Agulló-López, F
    Nonell, S
    Martí, C
    Brasselet, S
    Ledoux, I
    Zyss, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (49) : 12808 - 12817
  • [7] Synthesis of highly conjugated boron(III) subphthalocyanines
    delRey, B
    Torres, T
    [J]. TETRAHEDRON LETTERS, 1997, 38 (30) : 5351 - 5354
  • [8] Self-assembly of disk-shaped molecules to coiled-coil aggregates with tunable helicity
    Engelkamp, H
    Middelbeek, S
    Nolte, RJM
    [J]. SCIENCE, 1999, 284 (5415) : 785 - 788
  • [9] HIGH SYMMETRY CHIRAL MOLECULES
    FARINA, M
    MORANDI, C
    [J]. TETRAHEDRON, 1974, 30 (13) : 1819 - 1831
  • [10] Synthesis, self-assembly, and nonlinear optical properties of conjugated helical metal phthalocyanine derivatives
    Fox, JM
    Katz, TJ
    Van Elshocht, S
    Verbiest, T
    Kauranen, M
    Persoons, A
    Thongpanchang, T
    Krauss, T
    Brus, L
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (14) : 3453 - 3459