Micellar media for the efficient ring opening of epoxides with CN-, N3-, NO3-,NO2-, SCN-, Cl- and Br- catalyzed with Ce(OTf)4

被引：72

作者：

Iranpoor, N ^{[1
]}

Firouzabadi, H

Shekarize, M

机构：

[1] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran

[2] Res Inst Petr Ind, Addit Dept, Chem & Petrochem Div, Tehran, Iran

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2003年 / 1卷 / 04期

关键词：

D O I：

10.1039/b211697a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Micellar media are introduced for the efficient ring opening of epoxides with sodium salts of nucleophiles such as CN-, N-3(-), NO3-, NO2-, SCN-, Br- and Cl-, catalyzed with Ce(OTf)(4). This method is an efficient procedure for the synthesis of different beta-substituted alcohols under mild reaction conditions. The reaction with SCN- is an easy procedure for the high yielding preparation of epoxy sulfides.

引用

页码：724 / 727

页数：4

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