Kinetics study of the gas-phase reactions of cyclo-CF2CF2CHXCHX- (X = F, Cl) and cyclo-CF2CFClCCl2CH2- with OH radicals at 253-328 K

被引：6

作者：

Chen, L. ^{[1
]}

Mizukado, J. ^{[1
]}

Kutsuna, S. ^{[1
]}

Tokuhashi, K. ^{[1
]}

Sekiya, A. ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol AIST, Tsukuba, Ibaraki 3058569, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2007年 / 439卷 / 1-3期

关键词：

D O I：

10.1016/j.cplett.2007.03.070

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Rate constants for reactions of four halogenated cyclobutanes with OH radicals were determined by means of a relative rate method in an 11.5-dm(3) reaction chamber at 253-328 K: k(1) (cis-cyclo-CF2CF2CHFCHF-+ OH) = (1.03 +/- 0.42) x 10(-12) exp[-(1170 +/- 120)/T], k(2) (cis-cyclo-CF2CF2CHClCHCl-+ OH) = (7.73 +/- 1.04) x 10(-13) exp[-(600 +/- 40)/T], k(3) (trans-cyclo-CF2CF2CHClCHCl-+ OH) = (4.46 +/- 0.60) x 10(-13) exp[-(780 +/- 40)/T], and k(4) (cyclo-CF2CFClCCl2CH2-+ OH) = (2.44 +/- 0.90) x 10(-13) exp[-(1200 +/- 110)/T] cm(3) molecule(-1) s(-1). (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：40 / 45

页数：6

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