Lithium dimer formation in the Li-conducting garnets Li5+xBaxLa3-xTa2O12 (0 < x ≤ 1.6)

被引:111
作者
O'Callaghan, Michael P. [1 ]
Cussen, Edmund J. [1 ]
机构
[1] Univ Strathclyde, Dept Pure & Appl Chem, WestCHEM, Glasgow G1 1XL, Lanark, Scotland
关键词
D O I
10.1039/b700369b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The garnet system Li5+xBaxLa3-xTa2O12 shows an unprecedented Li+ content (x <= 1.6) and short Li-Li distances of ca 2.44 angstrom between majority occupied sites suggesting that the high Li+ mobility requires a complex cooperative mechanism.
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页码:2048 / 2050
页数:3
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