Cubic, hydrogen-bonded (10,3)-α networks in the family [C(NH2)3][N(CH3)4][XO4] (X = S, Cr, and Mo)

被引：38

作者：

Abrahams, BF ^{[1
]}

Haywood, MG ^{[1
]}

Hudson, TA ^{[1
]}

Robson, R ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Parkville, Vic 3010, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 45期

关键词：

coordination modes; crystal engineering; hydrogen bonds; structure elucidation; supramolecular chemistry;

D O I：

10.1002/anie.200461678

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It takes two: The complementary sulfate and guanidinium ions in [C(NH 2)3] [N(CH3)4][SO4] both act as 3-connecting nodes to give a 3D hydrogen-bonded network with the chiral (10,3)-a topology (see X-ray crystal structure; O red, S yellow, H pink, N blue, C black). In contrast, the 3-connected hydrogen-bonded network in the much-studied guanidinium sulfonates is 2D.

引用

页码：6157 / 6160

页数：4

共 18 条

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