Synthesis and characterization of functionalized MCM-41 with copper- and manganese-phenanthroline complexes

被引：30

作者：

Zheng, S ^{[1
]}

Gao, L ^{[1
]}

Guo, JK ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2000年 / 152卷 / 02期

关键词：

D O I：

10.1006/jssc.2000.8708

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The modification of the internal pore surface of mesoporous MCM-41 with 3-aminopropyl yielded amine group functionalized MCM-41, Copper(II) and manganese(II) phenanthroline complexes were grafted onto the functional MCM-41 via the coordination of the respective metal ion with the amine group, The metal ion complex functionalized mesoporous materials were characterized by powder X-ray diffraction (XRD), nitrogen adsorption/desorption at 77 K, solid state diffuse reflectance UV spectroscopy, and electron spin resonance (ESR) at 293 K as well as cyclic voltammetry. Preliminary studies suggested that the nature and electroactivity of metal ion complex functionalized MCM-41 differed significantly from those of metal ion complex impregnated MCM-41. (C) 2000 Academic Press.

引用

页码：447 / 452

页数：6

共 15 条

[1] Electrochemical study of polyaniline deposited on a titanium surface [J].

Arsov, LD .

JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 1998, 2 (04) :266-272

[2] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].

BECK, JS ;

VARTULI, JC ;

ROTH, WJ ;

LEONOWICZ, ME ;

KRESGE, CT ;

SCHMITT, KD ;

CHU, CTW ;

OLSON, DH ;

SHEPPARD, EW ;

MCCULLEN, SB ;

HIGGINS, JB ;

SCHLENKER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843

[3] HYDROCRACKING OF VACUUM GAS-OIL ON THE NOVEL MESOPOROUS MCM-41 ALUMINOSILICATE CATALYST [J].

CORMA, A ;

MARTINEZ, A ;

MARTINEZSORIA, V ;

MONTON, JB .

JOURNAL OF CATALYSIS, 1995, 153 (01) :25-31

[4] The synthesis of micrometer- and submicrometer-size spheres of ordered mesoporous oxide MCM-41 [J].

Grun, M ;

Lauer, I ;

Unger, KK .

ADVANCED MATERIALS, 1997, 9 (03) :254-&

[5] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].

KRESGE, CT ;

LEONOWICZ, ME ;

ROTH, WJ ;

VARTULI, JC ;

BECK, JS .

NATURE, 1992, 359 (6397) :710-712

[6] Manganese-bipyridine complex incorporated into mesoporous MCM-41 molecular sieves [J].

Luan, ZH ;

Xu, J ;

Kevan, L .

CHEMISTRY OF MATERIALS, 1998, 10 (11) :3699-3706

[7] Inclusion chemistry in periodic mesoporous hosts [J].

Moller, K ;

Bein, T .

CHEMISTRY OF MATERIALS, 1998, 10 (10) :2950-2963

[8] Synthesis and characterization of ferrocenyl-modified mesoporous silicates [J].

O'Brien, S ;

Keates, JM ;

Barlow, S ;

Drewitt, MJ ;

Payne, BR ;

O'Hare, D .

CHEMISTRY OF MATERIALS, 1998, 10 (12) :4088-4099

[9] ZEOLATES - A COORDINATION CHEMISTRY VIEW OF METAL-LIGAND BONDING IN ZEOLITE GUEST HOST INCLUSION-COMPOUNDS [J].

OZIN, GA ;

OZKAR, S .

CHEMISTRY OF MATERIALS, 1992, 4 (03) :511-521

[10]

Rao RR, 1999, CHEM COMMUN, P445

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