A new environmentally friendly process for the recovery of gold from electronic waste

被引:44
作者
Barbieri, Luisa [1 ]
Giovanardi, Roberto [1 ]
Lancellotti, Isabella [1 ]
Michelazzi, Marco [1 ]
机构
[1] Univ Modena & Reggio Emilia, Dept Mat Engn, I-41100 Modena, Italy
关键词
Cupric chloride; Ferric chloride; Chemical etching; Precious metals recovery; Electronic waste; CHLORIDE; OXIDATION; EFFLUENTS; IRON;
D O I
10.1007/s10311-009-0205-2
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new method for the recovery of precious metals, in particular gold, from electronic waste is proposed. This work focused on the research of an easily renewable etching agent, in order to make an environmentally friendly process possible. Two well known hydrometallurgical etching agents, FeCl3 and CuCl2, were evaluated in terms of efficiency and kinetics, testing solutions with different concentration of etchant and hydrochloric acid. The recovery of spent etching solutions was evaluated: promising results were found in the case of CuCl2, which can be completely restored by oxidation of the cuprous chloride formed during the etching using atmospheric oxygen.
引用
收藏
页码:171 / 178
页数:8
相关论文
共 15 条
[1]  
Bischoff A, 2004, P LBMA PREC MET C SH
[2]   Copper etching with cupric chloride and regeneration of waste etchant [J].
Cakir, O .
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 2006, 175 (1-3) :63-68
[3]   Mechanical recycling of waste electric and electronic equipment: a review [J].
Cui, JR ;
Forssberg, E .
JOURNAL OF HAZARDOUS MATERIALS, 2003, 99 (03) :243-263
[4]   The cyanide leaching gold recovery process is a nonsustainable technology with unacceptable impacts on ecosystems and humans: The disaster in Romania [J].
Korte, F ;
Spiteller, M ;
Coulston, F .
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 2000, 46 (03) :241-245
[5]   Thermodynamic properties of copper chloride complexes and copper transport in magmatic-hydrothermal solutions [J].
Liu, WH ;
McPhail, DC .
CHEMICAL GEOLOGY, 2005, 221 (1-2) :21-39
[6]  
LUNDSTROM M, 2008, HYDROMETALL IN PRESS
[7]   FERROUS-FERRIC OXIDATION IN ACIDIC MINERAL PROCESS EFFLUENTS - COMPARISON OF METHODS [J].
RAO, SR ;
FINCH, JA ;
KUYUCAK, N .
MINERALS ENGINEERING, 1995, 8 (08) :905-911
[8]  
Rem P.C., 2000, MAGN ELECT, V10, P85
[9]   The oxidation of ferrous iron in acidic mine effluents from the Iberian Pyrite Belt (Odiel Basin, Huelva, Spain):: Field and laboratory rates [J].
Sanchez Espana, Javier ;
Lopez Pamo, Enrique ;
Pastor, Esther Santofimia .
JOURNAL OF GEOCHEMICAL EXPLORATION, 2007, 92 (2-3) :120-132
[10]   Heavy metal partitioning from electronic scrap during thermal End-of-Life treatment [J].
Scharnhorst, Wolfram ;
Ludwig, Christian ;
Wochele, Jorg ;
Jolliet, Olivier .
SCIENCE OF THE TOTAL ENVIRONMENT, 2007, 373 (2-3) :576-584