From azides to nitro compounds in a few seconds using HOF-CH3CN

被引：85

作者：

Rozen, S ^{[1
]}

Carmeli, M ^{[1
]}

机构：

[1] Tel Aviv Univ, Raymond & Beverly Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 27期

关键词：

D O I：

10.1021/ja035616d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

HOF·CH3CN, a very efficient oxygen-transfer agent, was reacted with various azides to form the corresponding nitro compounds in excellent yields and in very short reaction times. The respective nitroso derivatives were found to be intermediates in this reaction. When the azides were reacted with MCPBA or DMDO, no reaction took place, and the starting materials were fully recovered. Copyright © 2003 American Chemical Society.

引用

页码：8118 / 8119

页数：2

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