Undoped diamond nanoparticles: origins of surface redox chemistry

被引：47

作者：

Holt, Katherine B. ^{[1
]}

机构：

[1] UCL, Dept Chem, London WC1H 0AJ, England

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2010年 / 12卷 / 09期

基金：

英国工程与自然科学研究理事会;

关键词：

BORON-DOPED DIAMOND; THIN-FILMS; ELECTROCHEMICAL PROPERTIES; RAMAN-SPECTRUM; NANODIAMOND; ELECTRODES; OXIDATION; HETEROGENEITY; MICROSCOPY; PARTICLES;

D O I：

10.1039/b920075d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This article discusses some of our recent work on the origins of redox activity of undoped nanodiamond (ND) powders, as well as reviewing some properties and applications of this material. The electrochemical activity is attributed to unsaturated bonding at the ND particle surface; hence the most recent understanding of the surface chemistry of these materials is discussed. The implications of the observed redox activity, especially for use in biological applications, are highlighted, along with future avenues of research.

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页码：2048 / 2058

页数：11

相关论文

共 59 条

[1] Optical properties of nanocrystalline diamond thin films [J].

Achatz, P ;

Garrido, JA ;

Stutzmann, M ;

Williams, OA ;

Gruen, DM ;

Kromka, A ;

Steinmüller, D .

APPLIED PHYSICS LETTERS, 2006, 88 (10)

[2] New prospects and frontiers of nanodiamond clusters [J].

Baidakova, Marina ;

Vul', Alexander .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2007, 40 (20) :6300-6311

[3] Influence of diamond powder particles on human gene expression [J].

Bakowicz-Mitura, Katarzyna ;

Bartosz, Grzegorz ;

Mitura, Stanislaw .

SURFACE & COATINGS TECHNOLOGY, 2007, 201 (13) :6131-6135

[4] Boron-doped diamond-based sensors: A review [J].

Chailapakul, Orawon ;

Siangproh, Weena ;

Tryk, Donald A. .

SENSOR LETTERS, 2006, 4 (02) :99-119

[5] Charge transfer equilibria between diamond and an aqueous oxygen electrochemical redox couple [J].

Chakrapani, Vidhya ;

Angus, John C. ;

Anderson, Alfred B. ;

Wolter, Scott D. ;

Stoner, Brian R. ;

Sumanasekera, Gamini U. .

SCIENCE, 2007, 318 (5855) :1424-1430

[6] Electrochemical oxidation of nitrite on nanodiamond powder electrode [J].

Chen, L. H. ;

Zang, J. B. ;

Wang, Y. H. ;

Bian, L. Y. .

ELECTROCHIMICA ACTA, 2008, 53 (08) :3442-3445

[7] The structure and electrochemical behavior of nitrogen-containing nanocrystalline diamond films deposited from CH4/N2/Ar mixtures [J].

Chen, QY ;

Gruen, DM ;

Krauss, AR ;

Corrigan, TD ;

Witek, M ;

Swain, GM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (01) :E44-E51

[8] Electroanalysis at diamond-like and doped-diamond electrodes [J].

Compton, RG ;

Foord, JS ;

Marken, F .

ELECTROANALYSIS, 2003, 15 (17) :1349-1363

[9] State of C-atoms on the modified nanodiamond surface [J].

Dementjev, A. ;

Maslakov, K. ;

Kulakova, I. ;

Korolkov, V. ;

Dolmatov, V. .

DIAMOND AND RELATED MATERIALS, 2007, 16 (12) :2083-2086

[10] Nonaromatic Core-Shell Structure of Nanodiamond from Solid-State NMR Spectroscopy [J].

Fang, XiaoWen ;

Mao, JingDong ;

Levin, E. M. ;

Schmidt-Rohr, Klaus .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (04) :1426-1435

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