Corrosion protection of iron by α,ω-diphosphonic acid layers

被引:43
作者
Felhösi, I [1 ]
Kálmán, E [1 ]
机构
[1] Hungarian Acad Sci, Chem Res Ctr, H-1525 Budapest, Hungary
关键词
protective layer; corrosion; phosphonic acids; impedance spectroscopy;
D O I
10.1016/j.corsci.2004.07.007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Protective layer formation of alpha,omega-diphosphono-alkane compounds on iron surface was studied. Layer formation proved to be a spontaneous process on iron, and can be accomplished by simple immersion into an aqueous solution of phosphono compounds, resulting in a thin dense multimolecular adsorption layer with a high corrosion protection effect. The mechanism of inhibition and time dependence of layer formation is presented. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:695 / 708
页数:14
相关论文
共 30 条
[1]   PHOSPHORUS DERIVATIVES OF FATTY ACIDS .1. PREPARATION AND PROPERTIES OF DIETHYL ACYLPHOSPHONATES [J].
ACKERMAN, B ;
JORDAN, TA ;
EDDY, CR ;
SWERN, D .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (17) :4444-4447
[2]   Stability of ω-functionalized self-assembled monolayers as a function of applied potential [J].
Boubour, E ;
Lennox, RB .
LANGMUIR, 2000, 16 (19) :7464-7470
[3]   Self assembled molecular monolayers on oxidized inhomogeneous aluminum surfaces [J].
Bram, C ;
Jung, C ;
Stratmann, M .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1997, 358 (1-2) :108-111
[4]   Studies of structural disorder of self-assembled thiol monolayers on gold by cyclic voltammetry and ac impedance [J].
Diao, P ;
Jiang, DL ;
Cui, XL ;
Gu, DP ;
Tong, RT ;
Zhong, B .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 464 (01) :61-67
[5]   Fractional coverage of defects in self-assembled thiol monolayers on gold [J].
Diao, P ;
Guo, M ;
Jiang, DL ;
Jia, ZB ;
Cui, XL ;
Gu, DP ;
Tong, RT ;
Zhong, B .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2000, 480 (1-2) :59-63
[6]   Kinetics of self-assembled layer formation on iron [J].
Felhösi, I ;
Telegdi, J ;
Pálinkás, G ;
Kálmán, E .
ELECTROCHIMICA ACTA, 2002, 47 (13-14) :2335-2340
[7]   Corrosion protection by self-assembly [J].
Felhösi, I ;
Kálmán, E ;
Póczik, P .
RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2002, 38 (03) :230-237
[8]  
FESER R, 1997, S EUR 97 TRONDH, V2, P291
[9]   SELF-ASSEMBLED MONOLAYERS OF LONG-CHAIN HYDROXAMIC ACIDS ON THE NATIVE OXIDES OF METALS [J].
FOLKERS, JP ;
GORMAN, CB ;
LAIBINIS, PE ;
BUCHHOLZ, S ;
WHITESIDES, GM ;
NUZZO, RG .
LANGMUIR, 1995, 11 (03) :813-824
[10]  
FURBETH W, 2003, P EUROCORR 2003 HUNG