Suppression of methanol crossover in Pt-dispersed polymer electrolyte membrane for direct methanol fuel cells

被引:27
作者
Uchida, H [1 ]
Mizuno, Y [1 ]
Watanabe, M [1 ]
机构
[1] Univ Yamanashi, Fac Engn, Lab Electrochem Energy Convers, Kofu, Yamanashi 4008511, Japan
关键词
D O I
10.1246/cl.2000.1268
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Suppression of methanol crossover in polymer electrolyte membranes is a key technology for direct methanol fuel cells (DMFCs). We have prepared a Nafion(R) 117 wherein platinum nanocrystals are highly dispersed and subsequently used it in a DMFC. This is expected to suppress the short-circuit reaction by oxidizing methanol at the Pt catalysts. Indeed, this is observed by the appreciable increase in the cathode potential, resulting from the reduced amount of methanol reaching the cathode.
引用
收藏
页码:1268 / 1269
页数:2
相关论文
共 15 条
[1]   TEMPERATURE-DEPENDENT METHANOL ELECTROOXIDATION ON WELL-CHARACTERIZED PT-RU ALLOYS [J].
GASTEIGER, HA ;
MARKOVIC, N ;
ROSS, PN ;
CAIRNS, EJ .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (07) :1795-1803
[2]   Structural and electrochemical characterization of binary, ternary, and quaternary platinum alloy catalysts for methanol electro-oxidation [J].
Gurau, B ;
Viswanathan, R ;
Liu, RX ;
Lafrenz, TJ ;
Ley, KL ;
Smotkin, ES ;
Reddington, E ;
Sapienza, A ;
Chan, BC ;
Mallouk, TE ;
Sarangapani, S .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (49) :9997-10003
[3]   Carbon supported and unsupported Pt-Ru anodes for liquid feed direct methanol fuel cells [J].
Liu, L ;
Pu, G ;
Viswanathan, R ;
Fan, QB ;
Liu, RX ;
Smotkin, ES .
ELECTROCHIMICA ACTA, 1998, 43 (24) :3657-3663
[4]  
NARAYANAN SR, 1995, ELECTROCHEMICAL S PV, V9523, P278
[5]  
REN X, 1995, ELECTROCHEMICAL SOC, V9523, P284
[6]   High performance direct methanol polymer electrolyte fuel cells [J].
Ren, XM ;
Wilson, MS ;
Gottesfeld, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) :L12-L15
[7]   INFLUENCES OF BOTH CARBON SUPPORTS AND HEAT-TREATMENT OF SUPPORTED CATALYST ON ELECTROCHEMICAL OXIDATION OF METHANOL [J].
UCHIDA, M ;
AOYAMA, Y ;
TANABE, M ;
YANAGIHARA, N ;
EDA, N ;
OHTA, A .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (08) :2572-2576
[8]  
Wainright JS, 1995, J ELECTROCHEM SOC, V42, P121
[9]   Analyses of self-humidification and suppression of gas crossover in Pt-dispersed polymer electrolyte membranes for fuel cells [J].
Watanabe, M ;
Uchida, H ;
Emori, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (04) :1137-1141
[10]   Self-humidifying polymer electrolyte membranes for fuel cells [J].
Watanabe, M ;
Uchida, H ;
Seki, Y ;
Emori, M ;
Stonehart, P .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (12) :3847-3852