Nickel-catalyzed formic acid reductions. A selective method for the reduction of nitro compounds.

被引：46

作者：

Gowda, DC ^{[1
]}

Gowda, ASP ^{[1
]}

Baba, AR ^{[1
]}

Gowda, S ^{[1
]}

机构：

[1] Univ Mysore, Dept Studies Chem, Mysore 570006, Karnataka, India

来源：

SYNTHETIC COMMUNICATIONS | 2000年 / 30卷 / 16期

关键词：

D O I：

10.1080/00397910008087439

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aliphatic and aromatic nitro compounds were selectively reduced to their corresponding amino derivatives in good yields using formic acid and raney nickel. This system is found to be compatible with several sensitive functionalities such as halogens, -OH, -OCH3, -CHO, -COCH3-COC6H5, -COOH, -COOC2H5, -CONH2, -CN, -CH=CH-COOH, -NHCOCH3. The reduction can be carried out not only with HCOOH but also with HCOONH4.

引用

页码：2889 / 2895

页数：7

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