Solvatochromic linear solvation energy relationships for solubility of O2 in various solvents

被引：21

作者：

Che, Y ^{[1
]}

Tokuda, K ^{[1
]}

Ohsaka, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 226, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1998年 / 71卷 / 03期

关键词：

D O I：

10.1246/bcsj.71.651

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Linear solvation energy relationships for solution of O-2 in 27 solvents have been examined. Multiple linear regression equations for mole fraction solubility of O-2 are developed based on Hildebrand's solubility parameter delta(H)(2) as well as the pi*, alpha and beta solvatochromic parameters describing the solvent polarizability/dipolarity, hydrogen bond acidity and hydrogen bond basicity, respectively. Use of the combination of these parameters enables the medium effect on solution of O-2 to be correlated and interpreted in a conceptually simple manner.

引用

页码：651 / 656

页数：6

共 21 条

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