Cocrystallization with acetylene: Molecular complexes with acetone and dimethyl sulfoxide

被引：58

作者：

Boese, R ^{[1
]}

Kirchner, MT

Billups, WE

Norman, LR

机构：

[1] Univ Essen Gesamthsch, Inst Anorgan Chem, D-45117 Essen, Germany

[2] Rice Univ, Dept Chem, Houston, TX 77251 USA

[3] Halliburton Co, Ctr Technol, Duncan, OK 73536 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 17期

关键词：

acetylene; crystal engineering; oligo diffractometry; structure elucidation; X-ray diffraction;

D O I：

10.1002/anie.200250634

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Different phases: Molecular complexes of acetylene and acetone or DMSO are formed simultaneously in different phases. Crystalline acetylene:actone 1:2 (A) and 1:1 (B), as well as acetylene:DMSO 2:1 (C) complexes have been obtained by in situ cocrystallization under pressure in a capillary with the use of an IR laser. The crystal structures may be interpreted as a frozen" situation of the liquids."

引用

页码：1961 / 1963

页数：3

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