catena-Poly[[bis(4-cyanobenzoato)-copper(II)]-μ-4,4′-bipyridine-κ2N:N′]

被引：14

作者：

He, HY ^{[1
]}

Zhu, LG ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803000989

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title polymeric complex, [Cu(C8H4NO2)(2)(C10H8N2)](n), the Cu-II center is located on an inversion center and surrounded by two N-donor molecules and two 4-cyanobenzoato ligands, which impose a square-planar environment on the metal. The spacer linker, 4,4'-bipyridine, is located on an inversion center and links adjacent metal atoms into a one-dimensional chain with a Cu...Cu separation of 11.218 (2) Angstrom.

引用

页码：O174 / O176

页数：3

共 11 条

[1]

*BRUK AXS INC, 1997, SMART SAINT SHELXTL

[2] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[3] From molecules to crystal engineering: Supramolecular isomerism and polymorphism in network solids [J].

Moulton, B ;

Zaworotko, MJ .

CHEMICAL REVIEWS, 2001, 101 (06) :1629-1658

[4] A homochiral metal-organic porous material for enantioselective separation and catalysis [J].

Seo, JS ;

Whang, D ;

Lee, H ;

Jun, SI ;

Oh, J ;

Jeon, YJ ;

Kim, K .

NATURE, 2000, 404 (6781) :982-986

[5]

Sheldrick G., 2017, SHELX2017, Programs for Crystal Structure Determination

[6]

Sheldrick G.M., 1996, SADABS VERSION 2008

[7] Synthesis, crystal structure and properties of a 4,4′-bipyridine bridged trigonal-bipyramidal copper homobinuclear complex with tris(2-aminoethyl)amine [J].

Xu, XY ;

Zheng, T ;

Ma, WX ;

Zhang, MX ;

Liu, QL ;

Grguric, SR ;

Dinovic, VM ;

Kaluderovic, GN ;

Sabo, TJ .

JOURNAL OF COORDINATION CHEMISTRY, 2002, 55 (06) :711-716

[8]

Yang R.-N., 1994, CHINESE J STRUC CHEM, V13, P45

[9]

Yang RN, 2001, CHIN J STRUCT CHEM, V20, P4

[10] Preparation, characterization, and X-ray crystal structure of a one-dimensional calcium-based coordination polymer with strong blue fluorescent emission [J].

Yuan, RX ;

Xiong, RG ;

Chen, ZF ;

You, XZ ;

Peng, SM ;

Lee, GH .

INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (08) :430-433

← 1 2 →