Reduction of solubilized multi-walled carbon nanotubes

被引:128
作者
Liu, LQ [1 ]
Qin, YJ [1 ]
Guo, ZX [1 ]
Zhu, DB [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
关键词
carbon nanotubes; infrared spectroscopy; Raman spectroscopy; X-ray photoelectron spectroscopy; reactivity;
D O I
10.1016/S0008-6223(02)00286-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, the chemical reduction of solubilized multi-walled carbon nanotubes by LiAlH4 was investigated. The amide groups on the nanotubes could be reduced to hydroxyl groups, which was confirmed by FTIR and XPS studies. The Raman spectroscopic investigation showed that the morphology of the nanotubes did not change after the reduction. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:331 / 335
页数:5
相关论文
共 23 条
[1]   Structure analysis of purified multiwalled carbon nanotubes [J].
Ando, Y ;
Zhao, X ;
Shimoyama, H .
CARBON, 2001, 39 (04) :569-574
[2]   Functionalization of carbon nanotubes by electrochemical reduction of aryl diazonium salts: A bucky paper electrode [J].
Bahr, JL ;
Yang, JP ;
Kosynkin, DV ;
Bronikowski, MJ ;
Smalley, RE ;
Tour, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (27) :6536-6542
[3]   Functionalization of carbon nanotubes with a metal-containing molecular complex [J].
Banerjee, S ;
Wong, SS .
NANO LETTERS, 2002, 2 (01) :49-53
[4]   Mercury(II) immobilized on carbon nanotubes: Synthesis, characterization, and redox properties [J].
Bond, AM ;
Miao, WJ ;
Raston, CL .
LANGMUIR, 2000, 16 (14) :6004-6012
[5]   Solution properties of single-walled carbon nanotubes [J].
Chen, J ;
Hamon, MA ;
Hu, H ;
Chen, YS ;
Rao, AM ;
Eklund, PC ;
Haddon, RC .
SCIENCE, 1998, 282 (5386) :95-98
[6]   Defunctionalization of functionalized carbon nanotubes [J].
Fu, KF ;
Huang, WJ ;
Lin, Y ;
Riddle, LA ;
Carroll, DL ;
Sun, YP .
NANO LETTERS, 2001, 1 (08) :439-441
[7]   Organic functionalization of carbon nanotubes [J].
Georgakilas, V ;
Kordatos, K ;
Prato, M ;
Guldi, DM ;
Holzinger, M ;
Hirsch, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (05) :760-761
[8]  
Hamon MA, 1999, ADV MATER, V11, P834, DOI 10.1002/(SICI)1521-4095(199907)11:10<834::AID-ADMA834>3.0.CO
[9]  
2-R
[10]   OPENING AND PURIFICATION OF CARBON NANOTUBES IN HIGH YIELDS [J].
HIURA, H ;
EBBESEN, TW ;
TANIGAKI, K .
ADVANCED MATERIALS, 1995, 7 (03) :275-276