Precise synthesis and properties of poly(isocyanide)s bearing porphyrins as a pendant group

被引：18

作者：

Takei, F

Onitsuka, K

Kobayashi, N

Takahashi, S

机构：

[1] Osaka Univ, Inst Sci & Ind Res, Osaka 5670047, Japan

[2] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 08期

关键词：

D O I：

10.1246/cl.2000.914

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aryl isocyanide bearing porphyrin has been prepared and polymerized by Pd-Pt mu-ethynediyl complex as an initiator to produce novel polymers. The UV-VIS absorption spectra suggest that porphyrin groups in their side chains are regularly arranged by the helical main chain of poly(isocyanide)s.

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页码：914 / 915

页数：2

相关论文

共 18 条

[1] Building molecular wires from the colours of life: conjugated porphyrin oligomers [J].

Anderson, HL .

CHEMICAL COMMUNICATIONS, 1999, (23) :2323-2330

[2] NEW POLYMERS CONTAINING PENDANT METALLOPORPHYRINS - RADICAL POLYMERIZATION OF 2-ACRYLOYLOXYMETHYLENE-5,10,15,20-TETRAPHENYLPORPHINATOMETALS [J].

AOTA, H ;

FUJII, H ;

HARADA, A ;

KAMACHI, M .

CHEMISTRY LETTERS, 1990, (05) :823-826

[3]

Graça M, 1999, CHEM COMMUN, P1771

[4]

Kadish K. M., 1999, PORPHYRIN HDB

[5] SYNTHESIS OF NEW POLYMERS CONTAINING PORPHYRINS IN THEIR SIDE-CHAINS - RADICAL POLYMERIZATIONS OF 5-[4-(ACRYLOYLOXY)PHENYL]-10,15,20-TRIPHENYLPORPHYRIN AND 5-[4-(METHACRYLOYLOXY)PHENYL]-10,15,20-TRIPHENYLPORPHYRIN [J].

KAMACHI, M ;

CHENG, XS ;

KIDA, T ;

KAJIWARA, A ;

SHIBASAKA, M ;

NAGATA, S .

MACROMOLECULES, 1987, 20 (11) :2665-2669

[6]

Kasha M., 1965, PURE APPL CHEM, V11, P371, DOI [10.1351/pac196511030371, DOI 10.1351/PAC196511030371]

[7] Supramolecular stacks of bis(imidazolyl)porphyrin through metal coordination [J].

Kobuke, Y ;

Miyaji, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (12) :3563-3569

[8] SYNTHESIS AND OPTICAL-PROPERTIES OF CONFORMATIONALLY CONSTRAINED TRIMERIC AND PENTAMERIC PORPHYRIN ARRAYS [J].

NAGATA, T ;

OSUKA, A ;

MARUYAMA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (08) :3054-3059

[9] HELICAL POLY(ISOCYANIDES) [J].

NOLTE, RJM .

CHEMICAL SOCIETY REVIEWS, 1994, 23 (01) :11-19

[10] ASYMMETRIC POLYMERIZATION [J].

OKAMOTO, Y ;

NAKANO, T .

CHEMICAL REVIEWS, 1994, 94 (02) :349-372