catena-Poly[di-μ1,1-azido-(1,10-phenanthroline)cadmium(II)]

被引：3

作者：

Chen, Feng ^{[1
,2
]}

Zheng, Fa-Kun ^{[1
]}

Liu, Guang-Ning ^{[1
,2
]}

Wu, Mei-Feng ^{[1
,2
]}

Guo, Guo-Cong ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

基金：

中国国家自然科学基金;

关键词：

MAGNETIC-PROPERTIES; 1D SYSTEMS; COMPLEXES; BEHAVIOR; CHAIN;

D O I：

10.1107/S1600536810019318

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title CdII compound, [Cd(N 3)2(C12H8N2)] n , contains a CdII atom, located on a twofold axis passing through the middle of the phenanthroline molecule, one azide ion and half of a 1,10-phenanthroline molecule. The CdII atom exhibits a distorted octa-hedral coordin-ation including one chelating 1,10-phenanthroline ligand and four azide ligands. The crystal structure features chains along the c direction in which azide groups doubly bridge two adjacent CdII atoms in an end-on (EO) mode. Inter-chain π-π stacking inter-actions, with centroid-centroid separations of 3.408 (2) Å between the central aromatic rings of 1,10-phenanthroline molecules, lead to a supra-molecular sheet parallel to the bc plane.

引用

页码：M758 / U442

页数：9

共 12 条

[1]

Abu-Youssef MAM, 2000, ANGEW CHEM INT EDIT, V39, P1624, DOI 10.1002/(SICI)1521-3773(20000502)39:9<1624::AID-ANIE1624>3.0.CO

[2]

2-7

[3] Synthesis, structure and properties of [Zn(dpa)(N3)2] and [Zn(dpa)(N3)(NO3)]2 (dpa=2,2'-dipyridylamine):: composition tailored architectures [J].