Spectroscopic investigation of the gel polymer electrolytes based on methyl methacrylate-styrene copolymers

被引：8

作者：

Jo, SI

Lee, S

Jeong, YB

Kim, DW

Sohn, HJ

机构：

[1] Hanbat Natl Univ, Dept Chem Technol, Taejon 305719, South Korea

[2] Seoul Natl Univ, Coll Engn, Sch Mat Sci & Engn, Seoul 151742, South Korea

来源：

ELECTROCHIMICA ACTA | 2004年 / 50卷 / 2-3期

关键词：

gel polymer electrolyte; methyl methacrylate-styrene copolymer; Raman spectroscopy; solid state Li-7 NMR; spin-spin relaxation time;

D O I：

10.1016/j.electacta.2004.01.100

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Gel polymer electrolytes composed of methy methacrylete-styrene copolymers (PMS) and electrolyte solution (LiTFSI in EC/DMC) were prepared and characterized. Depending on the molar composition of the copolymer, these gel polymer electrolytes exhibited different electrochemical and mechanical properties. In order to investigate the physical interactions among organic solvents, polymer, and lithium ions occurred in the gel polymer electrolyte, Raman spectroscopy and solid state Li-7 NMR spin-spin relaxation measurements were performed. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：327 / 330

页数：4

共 11 条

[1]

Gray F.M., 1997, POLYM ELECTROLYTES

[2] Electrochemical studies of gel polymer electrolytes based on methyl methacrylate-styrene copolymers [J].