The effect of tethered polymers on the conformation of a lipid membrane

被引:11
作者
Birshtein, TM [1 ]
Zhulina, EB [1 ]
机构
[1] UNIV PITTSBURGH,DEPT CHEM ENGN,PITTSBURGH,PA 15261
关键词
D O I
10.1002/mats.1997.040060608
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
We consider the effect of tethered macromolecules on the stability of the flat conformation of a lipid bilayer in a dense brush regime when anchored chains are significantly overlapped. On the basis of a scaling approach we have shown that redistribution of polymer chains from inner to outer layers reduces the free energy of the system and stabilizes spherically bent configurations of the membrane.
引用
收藏
页码:1169 / 1176
页数:8
相关论文
共 20 条
[1]   ADSORPTION OF CHAIN MOLECULES WITH A POLAR HEAD A-SCALING DESCRIPTION [J].
ALEXANDER, S .
JOURNAL DE PHYSIQUE, 1977, 38 (08) :983-987
[2]   CONFORMATIONS OF STAR-BRANCHED MACROMOLECULES [J].
BIRSHTEIN, TM ;
ZHULINA, EB .
POLYMER, 1984, 25 (10) :1453-1461
[3]  
BIRSHTEIN TM, 1985, MATH METHODS INVESTI, P4
[4]   ROLE OF ADSORBED POLYMER IN BILAYER ELASTICITY [J].
BROOKS, JT ;
MARQUES, CM ;
CATES, ME .
EUROPHYSICS LETTERS, 1991, 14 (07) :713-718
[5]   SPONTANEOUS CURVATURE OF MIXED-COPOLYMER BILAYERS [J].
DAN, N ;
SAFRAN, SA .
EUROPHYSICS LETTERS, 1993, 21 (09) :975-980
[6]   STAR SHAPED POLYMERS - A MODEL FOR THE CONFORMATION AND ITS CONCENTRATION-DEPENDENCE [J].
DAOUD, M ;
COTTON, JP .
JOURNAL DE PHYSIQUE, 1982, 43 (03) :531-538
[7]   INTERACTIONS BETWEEN POLYMERS AND SURFACTANTS [J].
DEGENNES, PG .
JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (22) :8407-8413
[8]   CONFORMATIONS OF POLYMERS ATTACHED TO AN INTERFACE [J].
DEGENNES, PG .
MACROMOLECULES, 1980, 13 (05) :1069-1075
[9]  
JOANNIC R, PREPRINT
[10]  
Lasic D. D., 1995, STEALTH LIPOSOMES