Cyclic water pentamers in triclinic crystals of brucinium L-glycerate

被引:21
作者
Bialonska, A [1 ]
Ciunik, Z [1 ]
Popek, T [1 ]
Lis, T [1 ]
机构
[1] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
关键词
D O I
10.1107/S0108270104031853
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Brucinium L-glycerate 4.75-hydrate, C23H27N2O4+.C3H5O4-.4.75H(2)O, was obtained by racemic resolution Of DL-glyceric acid. This is the first report of triclinic crystals containing brucine. The water and L-glycerate anions form tapes built up of pentamers formed by water and carboxy Oatoms, and this appears to be the reason for the low symmetry of the crystal.
引用
收藏
页码:O88 / O91
页数:4
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