Unified approach to the Bloch-Redfield theory and quantum Fokker-Planck equations

被引:53
作者
Yan, YJ [1 ]
Shuang, F
Xu, RX
Cheng, JX
Li, XQ
Yang, C
Zhang, HY
机构
[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
[2] Univ Sci & Technol China, Open Lab Bond Select Chem, Hefei, Peoples R China
关键词
D O I
10.1063/1.482018
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
By using a rather simple algebraic approach, we revisit and further bridge between two most commonly used quantum dissipation theories, the Bloch-Redfield theory and a class of Fokker-Planck equations. The nature of the common approximation scheme involving in these two theories is analyzed in detail. While the Bloch-Redfield theory satisfies the detailed-balance relation, we also construct a class of Fokker-Planck equations that satisfy the detailed-balance relation up to the second moments in phase-space. Developed is also a generalized Fokker-Planck equation that preserves the general positivity of the reduced density operator. Both T-1-relaxation and pure-T-2 dephasing are considered, and their temperature dependence is shown to be very different. Provided is also an analogy between the quantum pure-T-2 dephasing and the classical heat transport. (C) 2000 American Institute of Physics. [S0021- 9606(00)50430-9].
引用
收藏
页码:2068 / 2078
页数:11
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