Synthesis of a large-scale highly ordered porous carbon film by self-assembly of block copolymers

被引：783

作者：

Liang, CD ^{[1
]}

Hong, KL

Guiochon, GA

Mays, JW

Dai, S

机构：

[1] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 43期

关键词：

block copolymers; carbon; mesoporous materials; nanostructures; self-assembly;

D O I：

10.1002/anie.200461051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Made to order: The synthesis of well-defined porous carbon films involves four steps: 1) monomer-block copolymer film casting, 2) structure refining through solvent annealing, 3) polymerization of the carbon precursor, and 4) carbonization. The resulting films, such as that depicted, have potential as separation membranes, chemical sensors, and catalysts.

引用

页码：5785 / 5789

页数：5

共 30 条

[1] Synthesis and characterization of noble metal colloids in block copolymer micelles
Antonietti, M
Wenz, E
Bronstein, L
Seregina, M
[J]. ADVANCED MATERIALS, 1995, 7 (12) : 1000 - +
[2] Synthesis of metal nanoclusters within microphase-separated diblock copolymers: sodium carboxylate vs carboxylic acid functionalization
Clay, RT
Cohen, RE
[J]. SUPRAMOLECULAR SCIENCE, 1998, 5 (1-2): : 41 - 48
[3] Nanotubes as nanoprobes in scanning probe microscopy
Dai, HJ
Hafner, JH
Rinzler, AG
Colbert, DT
Smalley, RE
[J]. NATURE, 1996, 384 (6605) : 147 - 150
[4] Storage of hydrogen in single-walled carbon nanotubes
Dillon, AC
Jones, KM
Bekkedahl, TA
Kiang, CH
Bethune, DS
Heben, MJ
[J]. NATURE, 1997, 386 (6623) : 377 - 379
[5] Functionalized monolayers on ordered mesoporous supports
Feng, X
Fryxell, GE
Wang, LQ
Kim, AY
Liu, J
Kemner, KM
[J]. SCIENCE, 1997, 276 (5314) : 923 - 926
[6] FORMATION OF CARBON-FILMS ON CARBIDES UNDER HYDROTHERMAL CONDITIONS
GOGOTSI, YG
YOSHIMURA, M
[J]. NATURE, 1994, 367 (6464) : 628 - 630
[7] Aligned multiwalled carbon nanotube membranes
Hinds, BJ
Chopra, N
Rantell, T
Andrews, R
Gavalas, V
Bachas, LG
[J]. SCIENCE, 2004, 303 (5654) : 62 - 65
[8] Nanodomain control in copolymer thin films
Huang, E
Rockford, L
Russell, TP
Hawker, CJ
[J]. NATURE, 1998, 395 (6704) : 757 - 758
[9] MESOMORPHIC STATE OF POLY(VINYLPYRIDINE)-DODECYLBENZENESULFONIC ACID COMPLEXES IN BULK AND IN XYLENE SOLUTION
IKKALA, O
RUOKOLAINEN, J
TENBRINKE, G
TORKKELI, M
SERIMAA, R
[J]. MACROMOLECULES, 1995, 28 (21) : 7088 - 7094
[10] On the origins of morphological complexity in block copolymer surfactants
Jain, S
Bates, FS
[J]. SCIENCE, 2003, 300 (5618) : 460 - 464

← 1 2 3 →