Main group metal complexes of semicarbazones and thiosemicarbazones.: A structural review

被引：703

作者：

Casas, JS ^{[1
]}

García-Tasende, MS ^{[1
]}

Sordo, J ^{[1
]}

机构：

[1] Univ Santiago Compostela, Fac Farm, Dept Quim Inorgan, E-15706 Santiago De Compostela, Galicia, Spain

来源：

COORDINATION CHEMISTRY REVIEWS | 2000年 / 209卷

关键词：

main group metal complexes; thiosemicarbazonates; semicarbazonates; Zn; Cd and Hg complexes; Al; Ga; In and Tl complexes; Sn and Pb complexes; Bi complexes;

D O I：

10.1016/S0010-8545(00)00363-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structural aspects of the complexes formed by thiosemicarbazones (TSCs) and semicarbazones (SCs) with the metallic elements of Groups 12, 13, 14 and 15 are surveyed up to 1998. Descriptions of 71 structures containing neutral or deprotonated TSCs and ten with SCs include information on the metal-to-ligand bonds and the coordination behaviour of the ligand. The survey shows that TSCs are very versatile coordination agents with these accepters. (C) 2000 Elsevier Science B.V. All rights reserved.

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页码：197 / 261

页数：65

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