Synthesis and Diels-Alder reactivity of sulfinyl homo- and hetero-dienes obtained via enantiopure sulfenic acids

被引：13

作者：

Aversa, MC ^{[1
]}

Barattucci, A ^{[1
]}

Bonaccorsi, P ^{[1
]}

Giannetto, P ^{[1
]}

机构：

[1] Univ Messina, Dipartimento Chim Organ & Biol, Salita Sperone 31 Vill S Agata, I-98166 Messina, Italy

来源：

ARKIVOC | 2002年

关键词：

sulfenic acids; sulfinyl-dienes; cycloadditions; regioselectivity; stereoselectivity; chiral auxiliary removal;

D O I：

10.3998/ark.5550190.0003.b09

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This account is intended to provide a brief survey on our contribution in the field of enantiopure sulfinyl homo and hetero dienes which we are able to obtain via enantiopure sulfenic acids. The chemistry of these sulfinyl-dienes was mainly developed taking into account the practical importance of stereoselective homo and hetero Diels-Alder cycloadditions, able to supply useful intermediates in the synthesis of target molecules.

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页码：79 / 98

页数：20

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