A ferrocene-perfluoroarene molecular complex

被引：35

作者：

Beck, CM

Burdeniuc, J

Crabtree, RH

Rheingold, AL

Yap, GPA

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

[2] Univ Delaware, Dept Chem, Newark, DE 19716 USA

来源：

INORGANICA CHIMICA ACTA | 1998年 / 270卷 / 1-2期

关键词：

crystal structures; ferrocene complexes; perfluoroarene complexes;

D O I：

10.1016/S0020-1693(97)05999-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Perfluorophenanthrene and decamethylferrocene cocrystallize as a molecular adduct in monoclinic space group P2(1)/c with a=8.842(2), b=11.262(1), c=30.695(8) Angstrom, beta=95.89(2)degrees, V=3040.3(8) Angstrom(3), Z=4 The structure was refined to R=0.0537 for 1567 observed reflections. The perfluoroarene is twisted and chiral; the crystal is a racemate, however. (C) 1998 Elsevier Science S.A.

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页码：559 / 562

页数：4

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