Melt-intercalated starch acetate nanocomposite foams as affected by type of organoclay

Starch acetate nanocomposite foams with four organoclays (Cloisite 3013, 10A, 25A, and 20A) were prepared by melt-intercalation methods. The structural properties, thermal behaviors, and mechanical properties were characterized by X-ray diffraction (XPD), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetry analyses (TGA), and Instron universal testing machine. XRD results indicated that the intercalation of starch acetate into the nanoclay layers occurred for all four clays. The extent of intercalation depended on the type of organoclay and was exhibited in the sequence of Cloisite 30B >10A >25A >20A. SEM results indicated a decrease in cell size in the starch acetate foam matrix with the addition of nanoclay. Glass transition temperature (T-g) and onset temperatures of thermal degradation increased with the addition of organoclay into the starch acetate matrix. The incorporation of organoclays decreased significantly the compressibilities of starch acetate nanocoinposites and did not substantially affect their spring indices.