Effect of ultrasound on transport properties of nonaqueous solutions of lithium hexafluoroarsenate

被引：8

作者：

Afanas'ev, V. N. ^{[1
]}

Chekunova, M. D. ^{[1
]}

Tyunina, E. Yu. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Solut Chem, Ivanovo 153045, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2006年 / 80卷 / 12期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1134/S0036024406120119

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The speed of ultrasound in solutions of LiAsF6 in propylenecarbonate and gamma-butyrolactone was measured with an ultrasonic laser interferometer over a concentration range from 0.076 to 1.2 mol/kg at 273, 288, 298, 308, and 313 K. The solvation number h and molar adiabatic compressibility of the solvation complexes (beta(S,h) V (h)) of LiAsF6 in propylenecarbonate and gamma-butyrolactone were determined at concentrations typical of lithium batteries. Linear correlations between the molar physicochemical parameters of liquid-phase systems (time of propagation of ultrasound, fluidity, and electric conductivity) were established.

引用

页码：1929 / 1933

页数：5

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