Synthesis of enantiopure 1,2-diamine attached to cross-linked polystyrene and its application to an insoluble catalyst for asymmetric hydrogenation

被引：38

作者：

Itsuno, S ^{[1
]}

Tsuji, A ^{[1
]}

Takahashi, M ^{[1
]}

机构：

[1] Toyohashi Univ Technol, Dept Mat Sci, Toyohashi, Aichi 4418580, Japan

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 19期

关键词：

1,2-diamine; cross-linked polystyrene; asymmetric hydrogenation;

D O I：

10.1016/S0040-4039(03)00742-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel enantiopure 1,2-diamine (5) having two phenolic hydroxy groups was attached into chloromethylated polystyrene through benzyl ether linkage, which was used as a chiral ligand of the catalyst in asymmetric hydrogenation of acetophenone. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：3825 / 3828

页数：4

共 24 条

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