Preparation of thin films of a layered titanate by the exfoliation of CsxTi(2-x/4)□(x/4)O4

被引：58

作者：

Abe, R

Shinohara, K

Tanaka, A

Hara, M

Kondo, JN

Domen, K

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 226, Japan

[2] Nikon Corp, Sagamihara, Kanagawa 228, Japan

来源：

CHEMISTRY OF MATERIALS | 1998年 / 10卷 / 01期

关键词：

D O I：

10.1021/cm970481u

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Thin films composed of a layered titanate were prepared by a so-called soft-chemical method that took advantage of exfoliation of the layered material CsxTi(2-x/4)square(x/4)O(4). The exfoliated titanate sheets were easily oriented on a substrate by means of spin-coating. The prepared thin films had a layered structure, and the modification of them was possible by utilizing its ion-exchange and photocatalytic abilities.

引用

收藏

页码：329 / 333

页数：5

相关论文

共 15 条

[1] THE STABILITY AND STRUCTURE OF CSX[TI2-X-4-CLASS-X-4]O4, 0.61-LESS-THAN-X-LESS-THAN-0.65 [J].

GREY, IE ;

LI, C ;

MADSEN, IC ;

WATTS, JA .

JOURNAL OF SOLID STATE CHEMISTRY, 1987, 66 (01) :7-19

[2] SINGLE-LAYER MOS2 [J].

JOENSEN, P ;

FRINDT, RF ;

MORRISON, SR .

MATERIALS RESEARCH BULLETIN, 1986, 21 (04) :457-461

[3] LAYER-BY-LAYER ASSEMBLY OF INTERCALATION COMPOUNDS AND HETEROSTRUCTURES ON SURFACES - TOWARD MOLECULAR BEAKER EPITAXY [J].

KELLER, SW ;

KIM, HN ;

MALLOUK, TE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (19) :8817-8818

[4] VISIBLE-LIGHT PHOTOLYSIS OF HYDROGEN IODIDE USING SENSITIZED LAYERED SEMICONDUCTOR PARTICLES [J].

KIM, YI ;

SALIM, S ;

HUQ, MJ ;

MALLOUK, TE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (25) :9561-9563

[5] PREPARATION OF A SIO2-PILLARED K0.8FE0.8TI1.2O4 AND IR STUDY OF N-2 ADSORPTION [J].

KONDO, JN ;

SHIBATA, S ;

EBINA, Y ;

DOMEN, K ;

TANAKA, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (43) :16043-16046

[6] PHOTOCATALYTIC DECOMPOSITION OF WATER OVER NIO-K4NB6O17 CATALYST [J].

KUDO, A ;

TANAKA, A ;

DOMEN, K ;

MARUYA, K ;

AIKA, K ;

ONISHI, T .

JOURNAL OF CATALYSIS, 1988, 111 (01) :67-76

[7] NICKEL-LOADED K4NB6O17 PHOTOCATALYST IN THE DECOMPOSITION OF H2O INTO H-2 AND O-2 - STRUCTURE AND REACTION-MECHANISM [J].

KUDO, A ;

SAYAMA, K ;

TANAKA, A ;

ASAKURA, K ;

DOMEN, K ;

MARUYA, K ;

ONISHI, T .

JOURNAL OF CATALYSIS, 1989, 120 (02) :337-352

[8] INORGANIC ANALOGS OF LANGMUIR-BLODGETT FILMS - ADSORPTION OF ORDERED ZIRCONIUM 1,10-DECANEBISPHOSPHONATE MULTILAYERS ON SILICON SURFACES [J].

LEE, H ;

KEPLEY, LJ ;

HONG, HG ;

MALLOUK, TE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (02) :618-620

[9] TIO2(B) A NEW FORM OF TITANIUM-DIOXIDE AND THE POTASSIUM OCTATITANATE K2TI8O17 [J].

MARCHAND, R ;

BROHAN, L ;

TOURNOUX, M .

MATERIALS RESEARCH BULLETIN, 1980, 15 (08) :1129-1133

[10]

REBBAH H, 1979, MATER RES BULL, V14, P1125, DOI 10.1016/0025-5408(79)90206-X