Template- and vacuum-ultraviolet-assisted fabrication of a Ag-nanoparticle array on flexible and rigid substrates

被引:73
作者
Li, Jingze
Kamata, Kaori
Watanabe, Shigeru
Iyoda, Tomokazu
机构
[1] Tokyo Inst Technol, Div Integrated Mol Engn, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[2] Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan
[3] Kochi Univ, Fac Sci, Dept Mat Sci, Kochi 7808520, Japan
关键词
D O I
10.1002/adma.200602851
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A versatile, vacuum-ultraviolet-assisted macroscopic fabrication of hexagonally arranged Ag-nanoparticle arrays with controlled periodicity by using phase-segregated amphiphilic diblock copolymer films as templates is demonstrated on either flexible or rigid substrates. After Ag+ is selectively incorporated into the formed hydrophilic nanocylinders, both the photoreduction of Ag+ and a concomitant etching of the copolymer template are achieved by applying a 172 nm photon source (see figure).
引用
收藏
页码:1267 / +
页数:6
相关论文
共 54 条
[1]   Selective growth of cobalt nanoclusters in domains of block copolymer films [J].
Abes, JI ;
Cohen, RE ;
Ross, CA .
CHEMISTRY OF MATERIALS, 2003, 15 (05) :1125-1131
[2]   Nanoscale patterning of two metals on silicon surfaces using an ABC triblock copolymer template [J].
Aizawa, M ;
Buriak, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (17) :5877-5886
[3]   Block copolymer-templated chemistry on Si, Ge, InP, and GaAs surfaces [J].
Aizawa, M ;
Buriak, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (25) :8932-8933
[4]   Interaction of oxygen with silver at high temperature and atmospheric pressure: A spectroscopic and structural analysis of a strongly bound surface species [J].
Bao, X ;
Muhler, M ;
SchedelNiedrig, T ;
Schlogl, R .
PHYSICAL REVIEW B, 1996, 54 (03) :2249-2262
[5]   DNA-templated photoinduced silver deposition [J].
Berti, L ;
Alessandrini, A ;
Facci, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (32) :11216-11217
[6]   Laser photolysis formation of gold colloids in block copolymer micelles [J].
Bronstein, L ;
Chernyshov, D ;
Valetsky, P ;
Tkachenko, N ;
Lemmetyinen, H ;
Hartmann, J ;
Förster, S .
LANGMUIR, 1999, 15 (01) :83-91
[7]   Fabrication of metal-block-copolymer composite films by a palladium-catalyzed electroless nickel-plating process [J].
Cheng, YJ ;
Renker, S ;
Sun, ZC ;
Gutmann, JS .
MACROMOLECULAR RAPID COMMUNICATIONS, 2005, 26 (08) :613-619
[8]  
Cornelissen JJLM, 2002, ADV MATER, V14, P489, DOI 10.1002/1521-4095(20020404)14:7<489::AID-ADMA489>3.3.CO
[9]  
2-P
[10]   Spectroscopic investigation of nitrate-metal and metal-surfactant interactions in the solid AgNO3/C12EO10 and liquid-crystalline [M(H2O)n](NO3)2/C12EO10 systems [J].
Dag, Ö ;
Samarskaya, O ;
Tura, C ;
Günay, A ;
Çelik, Ö .
LANGMUIR, 2003, 19 (09) :3671-3676