Conformationally stressed phthalocyanines: the non-planarity of the 1,4,8,11,15,18,22,25-octaisopentyl derivative

被引:74
作者
Chambrier, I [1 ]
Cook, MJ [1 ]
Wood, PT [1 ]
机构
[1] Univ E Anglia, Sch Chem Sci, Norwich NR4 7TJ, Norfolk, England
关键词
D O I
10.1039/b006935n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An X-ray crystal structure determination reveals that 1,4,8,11,15,18,22,25-octaisopentylphthalocyanine adopts a saddle conformation, a geometry which shows modified spectroscopic properties and reduced photostability relative to planar ring structures.
引用
收藏
页码:2133 / 2134
页数:2
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