Determination of methyl- and ethylmercury compounds using gas chromatography atomic fluorescence spectrometry following aqueous derivatization with sodium tetraphenylborate

被引：31

作者：

Cai, Y ^{[1
]}

Monsalud, S

Furton, KG

机构：

[1] Florida Int Univ, Dept Chem, Miami, FL 33199 USA

[2] Florida Int Univ, SE Environm Res Ctr, Miami, FL 33199 USA

来源：

CHROMATOGRAPHIA | 2000年 / 52卷 / 1-2期

关键词：

gas chromatography; atomic fluorescence spectrometry detection; methylmercury and ethylmercury; sodium tetraphenylborate; fish and sediment samples;

D O I：

10.1007/BF02490797

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

An analytical procedure is described for the determination of methylmercury and ethylmercury compounds in fish and sediment samples using gas chromatography atomic fluorescence spectrometry following aqueous phenylation with sodium tetraphenylborate. The derivatization products were identified by gas chromatography mass spectrometry. The advantages of using phenylation with sodium tetraphenylborate over ethylation with sodium tetraethylborate are discussed. The validation of the analytical procedure was performed by analyzing standard reference material (DORM-2). Applications for the analysis of fish and sediment samples were carried out and compared to other techniques.

引用

页码：82 / 86

页数：5

共 25 条

[1]

Armstrong HL, 1999, ANAL CHIM ACTA, V390, P245

[2] DETERMINATION OF PICOGRAM LEVELS OF METHYLMERCURY BY AQUEOUS PHASE ETHYLATION, FOLLOWED BY CRYOGENIC GAS-CHROMATOGRAPHY WITH COLD VAPOR ATOMIC FLUORESCENCE DETECTION [J].