fac,trans-[(2,2′-bipyridine-N,N′)tricarbonylrhenium(I)]-μ-(4,4′-bipyridine)-N:N′-{chlorobis[1,2-phenylene-bis(dimethylarsine)]ruthenium(II)} bis(hexafluorophosphate) diacetone solvate

被引：5

作者：

Coe, BJ

McDonald, CI

Coles, SJ

Hursthouse, MB

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

[2] Univ Southampton, Dept Chem, EPSRC, Xray Crystallog Serv, Southampton SO17 1BJ, Hants, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2000年 / 56卷

关键词：

D O I：

10.1107/S0108270100008076

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of the heterobimetallic title compound, [ReRuCl(C10H16As2)(2)(C10H8N2)(2) (CO)(3)](PF6)(2) . 2C(3)H(6)O, is described. Both metal centres have pseudo-octahedral coordination geometries, with a facial arrangement of the carbonyl ligands at Re-I and a trans disposition of the diarsine ligands at Ru-II. The dihedral angle between the pyridyl rings of the 4,4'-bipyridine bridging ligand is 13.9 (6)degrees.

引用

页码：963 / 965

页数：3

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