Rare earth alkoxides as inorganic precursors for olefin polymerization: an alternative to traditional lanthanocene chemistry

被引：28

作者：

Gromada, J

Chenal, T

Mortreux, AE

Ziller, JW

Leising, F

Carpentier, JF

机构：

[1] ENSCL, CNRS, UPRESA 8010, Lab Catalyse Lille, F-59652 Villeneuve Dascq, France

[2] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

[3] Rhodia Rech, F-93308 Aubervilliers, France

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 22期

关键词：

D O I：

10.1039/b006941h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of the neodymium tert-butoxide [Nd-3(mu (3)-OBut)(2)(mu -OBut)(3)(OBut)(4)(THF)(2)] 1 with 1 equivalent of a dialkylmagnesium reagent affords an efficient catalyst for the pseudo-living polymerization of ethylene.

引用

页码：2183 / 2184

页数：2

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