Core-level anionic photofragmentation of OCS

被引:12
作者
Dang, LTN
Stolte, WC [1 ]
Öhrwall, G
SantAnna, MM
Dominguez-Lopez, I
Schlachter, AS
Lindle, DW
机构
[1] Univ Nevada, Dept Chem, Las Vegas, NV 89154 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Adv Light Source, Berkeley, CA 94720 USA
[3] Ctr Natl Metrol, Qreretaro 76900, Mexico
基金
美国国家科学基金会;
关键词
D O I
10.1016/S0301-0104(02)00784-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mass spectroscopy is used to study the formation of the S-, C-, and O- anions after photoexcitation of OCS in the vicinity of the S 2p and C 1s ionization thresholds. Anions are observed both below and above these thresholds. Because anion production is known to be suppressed at core-level shape resonances, the anion measurements serve as a suggestive and complementary tool for identifying above-threshold features in OCS photoabsorption. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:45 / 49
页数:5
相关论文
共 25 条
[1]   Decay of CS2 and OCS after sulphur is photoexcitation .2. Dissociation channels and kinematics [J].
Ankerhold, U ;
Esser, B ;
vonBusch, F .
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1997, 30 (05) :1207-1222
[2]  
[Anonymous], 1996, VUV and Soft X-ray PHotoionization
[3]  
[Anonymous], VUV SOFT XRAY PHOTOI
[4]  
[Anonymous], J ELECT SPECTROSC RE
[5]   CARBON AND OXYGEN KLL AND SULFUR LMM AUGER-SPECTRA OF OCS [J].
CARROLL, TX ;
JI, D ;
THOMAS, TD .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1990, 51 :471-486
[6]   HIGHLY EXCITED QUASISTABLE STATES OF NEUTRAL CO LYING UP TO THE DOUBLE-IONIZATION-ENERGY LEVEL [J].
DADOUCH, A ;
DUJARDIN, G ;
HELLNER, L ;
BESNARDRAMAGE, MJ ;
OLSSON, BJ .
PHYSICAL REVIEW A, 1991, 43 (11) :6057-6065
[7]   NEGATIVE-FRAGMENT-ION FORMATION BY PHOTON EXCITATION OF MOLECULES IN THE VICINITY OF THEIR CORE-IONIZATION AND DIRECT-DOUBLE-IONIZATION THRESHOLDS [J].
DUJARDIN, G ;
HELLNER, L ;
OLSSON, BJ ;
BESNARDRAMAGE, MJ ;
DADOUCH, A .
PHYSICAL REVIEW LETTERS, 1989, 62 (07) :745-748
[8]   High-resolution angular-resolved measurements of the fragmentation of the core-excited OCS molecule [J].
Erman, P ;
Karawajczyk, A ;
Rachlew, E ;
Stankiewicz, M ;
Franzen, KY .
PHYSICAL REVIEW A, 1997, 56 (04) :2705-2712
[9]   State selective photon induced formation of triply charged fragments from the core excited OCS molecule [J].
Erman, P ;
Karawajczyk, A ;
Rachlew, E ;
Stankiewicz, M ;
Franzén, KY .
JOURNAL OF CHEMICAL PHYSICS, 1997, 107 (24) :10827-10828
[10]   Multi-coincidence studies of fragmentations of core excited OCS molecules [J].
Erman, P ;
Karawajczyk, A ;
Rachlew, E ;
Stankiewicz, M ;
YoshikiFranzen, K .
ACTA PHYSICA POLONICA A, 1997, 91 (04) :769-773