Thermal behaviour of poly(allyl azide)

被引：26

作者：

Gaur, B ^{[1
]}

Lochab, B ^{[1
]}

Choudhary, V ^{[1
]}

Varma, IK ^{[1
]}

机构：

[1] Indian Inst Technol, Ctr Polymer Sci & Engn, New Delhi 110016, India

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2003年 / 71卷 / 02期

关键词：

curing studies; dipolarophiles; poly(allyl azide); poly(allyl chloride); thermal behaviour triazole;

D O I：

10.1023/A:1022843607664

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The paper describes the synthesis of low molecular mass poly(allyl chloride) (PAC) (M-n=856-3834 g mol(-1)) using Lewis acid (AlCl3, FeCl3, TiCl4) and Al powder. Branching in PAC was indicated on the basis of elemental analysis and H-1-NMR spectroscopy. Azidation of PAC could be carried out at 100degreesC by using NaN3 and DMSO as solvent. Curing of poly(allyl azide) (PAA) by cyclic dipolar addition reaction with EGDMA (ethylene glycol dimethacrylate, 5-45 phr) was investigated by differential scanning calorimetry and structure of cured polymer was confirmed by FTIR. A two-step mass loss was exhibited by uncured and cured PAA in nitrogen atmosphere. A mass loss of 20-28% (155-274degreesC) and 50-61% (330-550degreesC) was observed.

引用

页码：467 / 479

页数：13

共 12 条

[1]

[Anonymous], PROPELLANTS EXPLOS P

[2] Thermal decomposition of energetic materials 71: Structure-decomposition and kinetic relationships in flash pyrolysis of glycidyl azide polymer (GAP) [J].

Arisawa, H ;

Brill, TB .

COMBUSTION AND FLAME, 1998, 112 (04) :533-544

[3]

BALABAN AT, 1984, PHYSICAL METHODS HET, P46

[4] Studies on combustion of metallized RDX-based composite modified double-base propellants [J].

Divekar, CN ;

Asthana, SN ;

Singh, H .

JOURNAL OF PROPULSION AND POWER, 2001, 17 (01) :58-64

[5]

Eroglu MS, 1996, J APPL POLYM SCI, V61, P201

[6] Thermal decomposition of 3,3′-bis-azidomethyl-oxetane [J].

Lee, YJ ;

Tang, CJ ;

Kudva, G ;

Litzinger, TA .

JOURNAL OF PROPULSION AND POWER, 1998, 14 (01) :37-44

[7]

Manzara A. P., 1997, US Patent, Patent No. [5681904 A, 5681904]

[8] MODIFIED METHOD FOR KINETIC-ANALYSIS OF THERMOANALYTICAL DATA [J].

OZAWA, T .

JOURNAL OF THERMAL ANALYSIS, 1976, 9 (03) :369-373

[9]

PANDA SP, 1998, IS267 AM I AER ASTR, P1

[10]

PING W, 1996, 27 INT C ICT, P25

← 1 2 →