Synthesis of single-crystalline potassium-doped tungsten oxide nanosheets as high-sensitive gas sensors

被引:44
作者
Zhang, Bing
Liu, Jindun [1 ]
Guan, Shaokang
Wan, Yazhen
Zhang, Yongzhan
Chen, Rongfeng
机构
[1] Zhengzhou Univ, Sch Chem Engn, Zhengzhou 450002, Peoples R China
[2] Henan Acad Sci, Zhengzhou 450002, Peoples R China
[3] Zhengzhou Univ, Sch Mat Sci & Engn, Zhengzhou 450002, Peoples R China
关键词
tungsten oxide; nanosheets; chemical synthesis; gas sensitive properties;
D O I
10.1016/j.jallcom.2006.08.261
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The single-crystalline potassium-doped tungsten oxide nanosheets were prepared by simply heating a treated foil of tungsten. The as-prepared products were characterized using X-ray powder diffraction (XRD), scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, and selected-area electron diffraction (SAED). XRD and SAED results revealed that the products are pure, single-crystalline. The nanosheets width reaches to 30 mu m and thickness is about 80 nm. The nanosheets have high sensitivity, fast response time and good stability to H,S, acetone and other gases. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:55 / 58
页数:4
相关论文
共 20 条
[1]   Chemistry and properties of nanocrystals of different shapes [J].
Burda, C ;
Chen, XB ;
Narayanan, R ;
El-Sayed, MA .
CHEMICAL REVIEWS, 2005, 105 (04) :1025-1102
[2]   Solvothermal synthesis of tungsten oxide nanorod/nanowire/nanosheet [J].
Choi, HG ;
Jung, YH ;
Kim, DK .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (06) :1684-1686
[3]   Stable and highly sensitive gas sensors based on semiconducting oxide nanobelts [J].
Comini, E ;
Faglia, G ;
Sberveglieri, G ;
Pan, ZW ;
Wang, ZL .
APPLIED PHYSICS LETTERS, 2002, 81 (10) :1869-1871
[4]   Large-scale synthesis of ZnS nanosheets by the evaporation of ZnS nanopowders [J].
Fang, XS ;
Ye, CH ;
Peng, XS ;
Wang, YH ;
Wu, YC ;
Zhang, LD .
JOURNAL OF CRYSTAL GROWTH, 2004, 263 (1-4) :263-268
[5]   Self-catalyst growth and optical properties of novel SnO2 fishbone-like nanoribbons [J].
Hu, JQ ;
Bando, Y ;
Golberg, D .
CHEMICAL PHYSICS LETTERS, 2003, 372 (5-6) :758-762
[6]   Two-dimensional micrometer-sized single-crystalline ZnO thin nanosheets [J].
Hu, JQ ;
Bando, Y ;
Zhan, JH ;
Li, YB ;
Sekiguchi, T .
APPLIED PHYSICS LETTERS, 2003, 83 (21) :4414-4416
[7]   Crystalline structure, defects and gas sensor response to NO2 and H2S of tungsten trioxide nanopowders [J].
Jiménez, I ;
Arbiol, J ;
Dezanneau, G ;
Cornet, A ;
Morante, JR .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 93 (1-3) :475-485
[8]   Highly sensitive WO3 hollow-sphere gas sensors [J].
Li, XL ;
Lou, TJ ;
Sun, XM ;
Li, YD .
INORGANIC CHEMISTRY, 2004, 43 (17) :5442-5449
[9]   Large-scale synthesis of tungsten oxide nanowires with high aspect ratio [J].
Li, XL ;
Liu, JF ;
Li, YD .
INORGANIC CHEMISTRY, 2003, 42 (03) :921-924
[10]  
Li Y. B., 2002, APPL PHYS LETT, V82, P5084